TY  - JOUR
AU  - Shaheen R, Abaunza M. M.
PY  - 2014//
TI  - Large sulfur-isotope anomaly in nonvolcanic sulfate aerosol and its implications for the Archean atmosphere
T2  - 0027-8424
JO  - Proceedings of the National Academy of Sciences
SP  - 11979
EP  - 11983
VL  - 111
IS  - 33
N2  - Sulfur-isotopic anomalies have been used to trace the evolution of oxygen in the Precambrian atmosphere and to document past volcanic eruptions. High-precision sulfur quadruple isotope measurements of sulfate aerosols extracted from a snow pit at the South Pole (1984-2001) showed the highest S-isotopic anomalies ({Delta}33S = +1.66{per thousand} and {Delta}36S = +2{per thousand}) in a nonvolcanic (1998-1999) period, similar in magnitude to Pinatubo and Agung, the largest volcanic eruptions of the 20th century. The highest isotopic anomaly may be produced from a combination of different stratospheric sources (sulfur dioxide and carbonyl sulfide) via SOx photochemistry, including photoexcitation and photodissociation. The source of anomaly is linked to super El Nino Southern Oscillation (ENSO) (1997-1998)-induced changes in troposphere-stratosphere chemistry and dynamics. The data possess recurring negative S-isotope anomalies ({Delta}36S = -0.6 {+/-} 0.2{per thousand}) in nonvolcanic and non-ENSO years, thus requiring a second source that may be tropospheric. The generation of nonvolcanic S-isotopic anomalies in an oxidizing atmosphere has implications for interpreting Archean sulfur deposits used to determine the redox state of the paleoatmosphere.
SN  - 0027-8424
UR  - http://dx.doi.org/10.1073/pnas.1406315111
N1  - exported from refbase (http://publi.ipev.fr/polar_references/show.php?record=5972), last updated on Wed, 03 Jul 2024 18:04:42 +0200
ID  - ShaheenR2014
ER  -