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J Mathurin, E Dartois, C Engrand, J Duprat, A Deniset- Besseau, A Dazzi, Y Kebukawa, T Noguchi, D Troadec |
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Nanometre-scale infrared chemical imaging (AFM-IR) of organic matter in ultra-carbonaceous Antarctic micrometeorites (UCAMMS) and future analyses of Hayabusa 2 samples. |
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Peer-reviewed symposium |
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2020 |
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Lunar and Planetary Science, id 1983 |
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Introduction: The chemical composition of organic matter (OM) in interplanetary samples (meteorites and micrometeorites) is suitably characterized by the distribution of the different chemical bonds using infrared (IR) vibrational spectroscopy (see e.g. [1]). Classical IR microscopy provides a global view of the dust grain chemical structure content but remains limited by the diffraction, with typical spot sizes sampling a few micrometers in the mid-IR range. This spatial resolution limitation is well above that of complementary techniques such as isotopic imaging with NanoSIMS or transmission electron or X-ray microscopy techniques. These techniques reveal mineralogical, chemical and isotopic heterogeneities at the sub-micron scale but do not give full access to the distribution of the various chemical bonds. The IR diffraction limitation can be circumvented by using AFM-IR microscopy. This technique opens a new window for studies of OM at ten to tens of nanometer scales and will be of importance for studies of the samples from carbonaceous asteroid Ryugu, returned by the Hayabusa 2 space probe in December 2020. AFM-IR is now a well-established microscopy technique in the vibrational field. It combines an atomic force microscope (AFM) and a tunable IR source to detect photo-thermal effect and access chemical information down to a nanoscale resolution [2]. This technique is now applied in a wide diversity of scientific fields [3], and was recently used to analyze extraterrestrial OM [4, 5]. We report here on recent results obtained on imaging two UltraCarbonaceous Antarctic MicroMeteorites (UCAMMs) using AFM-IR [5]. A small fraction of the Antarctic micrometeorites from the Concordia collection consists in UCAMMs, particles with extreme concentrations in OM, most of them exhibiting large deuterium excesses [6]. UCAMMs are also found in Japanese interplanetary dust collections [7-9]. These UCAMMs most likely originate from the surface of small icy bodies in the outer regions of the solar system [1,6,7,10]. The large OM fraction of UCAMMs (considerably higher than in the most carbon-rich meteorites) enables direct analyses without the pre-treatment generally applied to extract the OM from other meteoritic samples, and give access to unaltered chemical maps of the intimate association of minerals and organics. |
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1120 |
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7912 |
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J Rojas, J Duprat, E Dartois, T-D Wu, C Engrand, B Augé, J Mathurin, B Guerin, J-L Guerquin-Kern, Ph Boduch, H Rothard |
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Title |
Isotopic analyses of ion irradiation-induced organic residues, clues on the formation of organics from UCAMMS |
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Peer-reviewed symposium |
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2020 |
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Lunar and Planetary Science, id 1630 |
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51 |
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1630 |
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Introduction: UltraCarbonaceous Antarctic Mi-croMeteorites (UCAMMs) are interplanetary dust particles that exhibit large concentrations of organic matter with high N concentrations and extreme D/H ratios [1-4]. The mineralogy, the elemental and isotopic composition of UCAMMs indicate that they most likely originate from the cometary reservoir [1, 2, 5]. Most UCAMMs exhibit large variations on D/H, 15 N/ 14 N and 13 C/ 12 C ratios at the micron or sub-micron scale. These isotopic fractionations are carried by the organic matter and their origin is still an open question. We showed that the precursors of UCAMMs can be formed by irradiation with high energy ions of N-rich ice mixtures with hydrocarbons, a process likely to take place at the surface of icy bodies orbiting beyond a nitrogen snow line and irradiated by galactic cosmic rays [2, 6]. Recent experimental simulations showed that the irradiation itself does not induce large D fractionation, but that the refractory organic residue resulting from irradiation of isotopically heterogeneous ice mixtures can exhibit large D/H spatial variation at the micron scale [7]. We performed a new series of experiments on D, 15 N and 13 C labelled ices to study the transmission of the isotopic labelled ice layers to the irradiation-induced residue. Material and method: Irradiation experiments of ices were conducted with the low-energy beam (Irrsud, 0.5-1 MeV/n) at GANIL (Caen, France). We used the IGLIAS experimental setup [8] which allows to deposit and irradiate complex ice films mixtures on substrate windows held at temperatures ranging from 8K to 300K (Figure 1). The evolution of the ices during the irradiation was monitored in situ with a Brucker Vertex 70v Fourier transform infrared (FTIR) spectrometer. The gas mixtures deposited are controlled with a Quadrupole Mass Spectrometer (QMS). We followed the same protocol as described in [7]. We first irradiated a mixture of ices made of two equally thick layers of 14 N2-CH4 (90:10) of about 5 µm each surrounding a thin layer of isotopically labeled (in D, 13 C and 15 N) ice with a thickness of about 0.2 µm. The ice films were formed by gas injections on ZnSe windows at 8K. The thickness of the central isotopically labeled ice layer was estimated from the volume of gases injected (i.e. 2% of the total thickness). The overall thickness of the ice sandwiches (11 µm) were |
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1120 |
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yes |
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7913 |
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J Rojas, J Duprat, L R Nittler, J Mathurin, E Dartois, C Engrand, N Bardin, A Dazzi, A Deniset-Besseau, M Godard, J-L Guerquin-Kern, B Guerin, S Moste- Faoui, L Rémusat, R M Stroud, T-D Wu |
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Title |
The isotopic diversity of ultracarbonaceous Antarctic micrometeorites, a coupled nanosims and afmir study |
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Peer-reviewed symposium |
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2020 |
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Lunar and Planetary Science, : id 1614 |
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2326 |
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1120 |
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yes |
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7914 |
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Isabelle Badenhausser, Lise Chambrin, Marc Lebouvier |
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Title |
Guide d'identification des plantes des îles sub-Antarctiques Crozet et Kerguelen |
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Book |
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2020 |
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1e édition, imprimerie nouvelle biard |
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151 p |
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136 |
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978-2-7380-1440-5 |
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yes |
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7975 |
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Julie Mestre, Matthieu Authier, Yves Cherel, Rob Harcourt, Clive R. McMahon, Mark A. Hindell, Jean-Benoît Charrassin, Christophe Guinet |
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Title |
Decadal changes in blood δ13C values, at-sea distribution, and weaning mass of southern elephant seals from Kerguelen Islands |
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Journal |
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2020 |
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Proceedings of the Royal Society B: Biological Sciences |
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287 |
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1933 |
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20201544 |
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bio-logging decadal change foraging habitat Indian sector of the Southern Ocean population strategies stable isotopes |
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Changes in the foraging environment and at-sea distribution of southern elephant seals from Kerguelen Islands were investigated over a decade (2004–2018) using tracking, weaning mass, and blood δ13C values. Females showed either a sub-Antarctic or an Antarctic foraging strategy, and no significant shift in their at-sea distribution was detected between 2004 and 2017. The proportion of females foraging in sub-Antarctic versus Antarctic habitats did not change over the 2006–2018 period. Pup weaning mass varied according to the foraging habitat of their mothers. The weaning mass of sub-Antarctic foraging mothers' pups decreased by 11.7 kg over the study period, but they were on average 5.8 kg heavier than pups from Antarctic foraging mothers. Pup blood δ13C values decreased by 1.1‰ over the study period regardless of their sex and the presumed foraging habitat of their mothers. Together, these results suggest an ecological change is occurring within the Indian sector of the Southern Ocean with possible consequences on the foraging performance of southern elephant seals. We hypothesize that this shift in δ13C is related to a change in primary production and/or in the composition of phytoplankton communities, but this requires further multidisciplinary investigations. |
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109,1201 |
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Bachelor's thesis |
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8006 |
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Sylvie Duchesne, R Bravina, V POPOV, S Kolodeznikov, P Gérard, V Myglan, Ch Hochstrasser-Petit, L Romanova, M Petit, N Kirianov, A Alexeev, L Alekseeva, A Riberon, E Crubézy |
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Title |
Frozen graves of Yakutia, a chronological sequence |
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Journal |
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2020 |
Publication |
VESTNIK ARHEOLOGII, ANTROPOLOGII I ETNOGRAFII |
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Volume |
4 |
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Pages |
120-130 |
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Keywords |
artefacts Christianization chronology funeral practices modern period soil burial Yakutia Yakuts |
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Abstract |
Distribution, cultural and chronological attribution of frozen graves of Yakutia between the beginning of 17th and end of 19th century. The funerary rites and the artefacts allow to differentiate four chrono-cultural periods (before 1700 AD, from 1700 to 1750 AD, from 1750 to 1800 AD and after 1800 AD) which could be associated with historical events: opening of the trading post of Nertchinsk, expansion of the Kangalasky clan, economic collapse, generalization of Christianization. |
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1038 |
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yes |
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8012 |
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Sarah C. Davidson, Gil Bohrer, Eliezer Gurarie, Scott LaPoint, Peter J. Mahoney, Natalie T. Boelman, Jan U. H. Eitel, Laura R. Prugh, Lee A. Vierling, Jyoti Jennewein, Emma Grier, Ophélie Couriot, Allicia P. Kelly, Arjan J. H. Meddens, Ruth Y. Oliver, Roland Kays, Martin Wikelski, Tomas Aarvak, Joshua T. Ackerman, José A. Alves, Erin Bayne, Bryan Bedrosian, Jerrold L. Belant, Andrew M. Berdahl, Alicia M. Berlin, Dominique Berteaux, Joël Bêty, Dmitrijs Boiko, Travis L. Booms, Bridget L. Borg, Stan Boutin, W. Sean Boyd, Kane Brides, Stephen Brown, Victor N. Bulyuk, Kurt K. Burnham, David Cabot, Michael Casazza, Katherine Christie, Erica H. Craig, Shanti E. Davis, Tracy Davison, Dominic Demma, Christopher R. DeSorbo, Andrew Dixon, Robert Domenech, Götz Eichhorn, Kyle Elliott, Joseph R. Evenson, Klaus-Michael Exo, Steven H. Ferguson, Wolfgang Fiedler, Aaron Fisk, Jérôme Fort, Alastair Franke, Mark R. Fuller, Stefan Garthe, Gilles Gauthier, Grant Gilchrist, Petr Glazov, Carrie E. Gray, David Grémillet, Larry Griffin, Michael T. Hallworth, Autumn-Lynn Harrison, Holly L. Hennin, J. Mark Hipfner, James Hodson, James A. Johnson, Kyle Joly, Kimberly Jones, Todd E. Katzner, Jeff W. Kidd, Elly C. Knight, Michael N. Kochert, Andrea Kölzsch, Helmut Kruckenberg, Benjamin J. Lagassé, Sandra Lai, Jean-François Lamarre, Richard B. Lanctot, Nicholas C. Larter, A. David M. Latham, Christopher J. Latty, James P. Lawler, Don-Jean Léandri-Breton, Hansoo Lee, Stephen B. Lewis, Oliver P. Love, Jesper Madsen, Mark Maftei, Mark L. Mallory, Buck Mangipane, Mikhail Y. Markovets, Peter P. Marra, Rebecca McGuire, Carol L. McIntyre, Emily A. McKinnon, Tricia A. Miller, Sander Moonen, Tong Mu, Gerhard J. D. M. Müskens, Janet Ng, Kerry L. Nicholson, Ingar Jostein Øien, Cory Overton, Patricia A. Owen, Allison Patterson, Aevar Petersen, Ivan Pokrovsky, Luke L. Powell, Rui Prieto, Petra Quillfeldt, Jennie Rausch, Kelsey Russell, Sarah T. Saalfeld, Hans Schekkerman, Joel A. Schmutz, Philipp Schwemmer, Dale R. Seip, Adam Shreading, Mónica A. Silva, Brian W. Smith, Fletcher Smith, Jeff P. Smith, Katherine R. S. Snell, Aleksandr Sokolov, Vasiliy Sokolov, Diana V Solovyeva, Mathew S. Sorum, Grigori Tertitski, J. F. Therrien, Kasper Thorup, T. Lee Tibbitts, Ingrid Tulp, Brian D. Uher-Koch, Rob S. A. van Bemmelen, Steven Van Wilgenburg, Andrew L. Von Duyke, Jesse L. Watson, Bryan D. Watts, Judy A. Williams, Matthew T. Wilson, James R. Wright, Michael A. Yates, David J. Yurkowski, Ramūnas Žydelis, Mark Hebblewhite |
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Title |
Ecological insights from three decades of animal movement tracking across a changing Arctic |
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2020 |
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Science |
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Volume |
370 |
Issue |
6517 |
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712-715 |
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388 |
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8024 |
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Aymeric Fromant, Charles-André Bost, Paco Bustamante, Alice Carravieri, Yves Cherel, Karine Delord, Yonina H. Eizenberg, Colin M. Miskelly, John P. Y. Arnould |
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Temporal and spatial differences in the post-breeding behaviour of a ubiquitous Southern Hemisphere seabird, the common diving petrel |
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2020 |
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Royal Society Open Science |
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7 |
Issue |
11 |
Pages |
200670 |
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Keywords |
migration moult non-breeding Procellariiformes Southern Ocean stable isotopes |
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The non-breeding period plays a major role in seabird survival and population dynamics. However, our understanding of the migratory behaviour, moulting and feeding strategies of non-breeding seabirds is still very limited, especially for small-sized species. The present study investigated the post-breeding behaviour of three distant populations (Kerguelen Archipelago, southeastern Australia, New Zealand) of the common diving petrel (CDP) (Pelecanoides urinatrix), an abundant, widely distributed zooplanktivorous seabird breeding throughout the southern Atlantic, Indian and Pacific oceans. The timing, geographical destination and activity pattern of birds were quantified through geolocator deployments during the post-breeding migration, while moult pattern of body feathers was investigated using stable isotope analysis. Despite the high energetic cost of flapping flight, all the individuals quickly travelled long distances (greater than approx. 2500 km) after the end of the breeding season, targeting oceanic frontal systems. The three populations, however, clearly diverged spatially (migration pathways and destinations), and temporally (timing and duration) in their post-breeding movements, as well as in their period of moult. Philopatry to distantly separated breeding grounds, different breeding phenologies and distinct post-breeding destinations suggest that the CDP populations have a high potential for isolation, and hence, speciation. These results contribute to improving knowledge of ecological divergence and evolution between populations, and inform the challenges of conserving migratory species. |
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394 |
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yes |
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8029 |
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Tartu S., Blévin P., Bustamante P., Angelier A., Bech C., Bustnes J.o., Gabrielsen G.w., Goutte A., Moe B., Sauser C., Sire J., Barbraud C., Chastel O |
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Drivers and trends of mercury exposure in Svalbard kittiwakes in a warming context over 17 years |
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Peer-reviewed symposium |
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2020 |
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Setac north-america 41st annual meeting, fort worth, tx, usa (15-19 november 2020) virtual |
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330 |
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yes |
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8034 |
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Chastel O |
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Contaminants of Growing Concern: Poly- and Perfluoroalkylated Substances (PFAS) and their Physiological Consequences in Seabirds |
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Peer-reviewed symposium |
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2020 |
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SETAC North-America 41st Annual Meeting, Fort Worth, TX, USA (15-19 November 2020), virtual |
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330 |
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yes |
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8035 |
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