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Abstract: To distinguish between Fe(II) and Fe(III) species in atmospheric water samples, we have adapted an analytical procedure based on the formation of a specific complex between Fe(II) and ferrozine (FZ) on a chromatographic column. After elution of Fe(III), the Fe(II) complex is recovered with water-methanol (4:1). The possibility of trace iron measurements in this complex medium by graphite-furnace atomic-absorption spectrometry has been investigated. A simplex optimization routine was required to complete the development of the analytical method.
Programme: 1026
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Massom R.A., Hill K., Barbraud C., Adams N., Ancel A., Emmerson L. & Pook M.J. (2009). Mar. Ecol. Prog. Ser., 374, 243–257.
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