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Chulliat, A.; Blanter, E.; Le Mouël, J.-L.; Shnirman, M. (2005). On the seasonal asymmetry of the diurnal and semidiurnal geomagnetic variations. J. Geophys. Res., 110.
Abstract: The diurnal and semidiurnal variations of the geomagnetic field are investigated at 18 observatories using long series of hourly values (up to 97 years at Sitka). The seasonal variations of amplitude of the 12-hour and 24-hour lines are obtained for the H and Z components using a 28-day sliding window. The Fourier analysis is performed using either all days within the window or only the five quietest days. At midlatitudes a strong lack of symmetry about the summer solstice is observed for both lines and both components. This effect is enhanced when selecting quiet days. When averaged over the entire series, the sign of this seasonal asymmetry is the same at 9 out of 10 midlatitude observatories for both lines and for a given component; it is opposite for the H and Z components. Such a coherent seasonal asymmetry is not found at low and high latitudes. At high latitudes a strong annual variation is found inside the polar caps, while a strong semiannual variation is found in the auroral zones. When selecting quiet days, these two effects are weaker, and the seasonal asymmetry becomes comparable to that at midlatitudes. At all latitudes the year-to-year variations of the seasonal asymmetry are uncorrelated with solar activity. It is suggested that lower thermospheric winds may have a similar seasonal asymmetry between spring and autumn equinoxes. Such an asymmetry is present in the published literature but has been overlooked. Possible causes for this wind asymmetry are reviewed.
Keywords: daily variation; lower thermospheric winds; ionospheric dynamo; current system; geomagnetic activity; equinoxes; 1555 Geomagnetism and Paleomagnetism: Time variations: diurnal to decadal; 2437 Ionosphere: Ionospheric dynamics; 3369 Atmospheric Processes: Thermospheric dynamics; 3389 Atmospheric Processes: Tides and planetary waves
Programme: 139
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Pazmiño, A.F.; Godin-Beekmann, S.; Ginzburg, M.; Bekki, S.; Hauchecorne, A.; Piacentini, R.D.; Quel, E.J. (2005). Impact of Antarctic polar vortex occurrences on total ozone and UVB radiation at southern Argentinean and Antarctic stations during 1997–2003 period. J. Geophys. Res., 110.
Abstract: The evolution of total ozone and surface UV radiation over some stations in the southern region of South America and in Antarctica in relationship with polar vortex occurrences is analyzed using Total Ozone Mapping Spectrometer total ozone measurements and local surface UV data for the 1997–2003 period. The data are classified as a function of the position of the stations with respect to the polar vortex using equivalent latitude at 550 K isentropic level. The study of vortex occurrences showed that Ushuaia station (54.9°S) was located ?40% of the cases in the edge of the vortex and 5% inside the vortex core during the winter-spring period. Concerning the Marambio (62.2°S) and Dumont d'Urville (66.4°S) stations, located on the shore of the Antarctic continent, the analysis shows a zonal asymmetry with respect to the center of the vortex. Marambio is located around 60% of the time inside the vortex, while Dumont d'Urville is predominantly at the edge of or outside the vortex. The evolution of the equivalent latitude of the stations in the anomalous 2002 winter presents a different behavior with respect to other years in the 1997–2003 period. The persistence of the vortex core above the stations is in average 1.8 days over Ushuaia and 7.1 days over Marambio in October during the 1997–2003 period with corresponding mean total ozone columns of 208.2 and 181.4 Dobson units, respectively. When the stations are inside the vortex, the total ozone columns are generally larger at Ushuaia than at Marambio in October during the 1997–2003 period. Finally, the impact of ozone-depleted air mass occurrences on ultraviolet radiation is evaluated by relating total ozone and UV erythemal dose measured at the stations. Twofold or threefold UV dose increases were reached in the 55°–65° southern latitude region during vortex overpasses, reaching maximum UV dose around 5 kJ/m2. The average increase of UV dose could be computed at the stations considered in the study when the measurement sampling and the number of vortex occurrences was sufficient. An average increase of 67.6% of the erythemal UV dose was found in October at Ushuaia over the years 1997, 1998, and 2000. This value is strongly weighted by vortex occurrences over the station in 2000. At Marambio an average UV increase of 47.4% was found over the years 1999 and 2000. Midlatitude stations like Comodoro Rivadavia (45.8°S) are generally little affected by vortex intrusions. Nevertheless, the maximum UV dose can increase by more than 50% when the vortex passes over the station.
Keywords: polar ozone loss; UV radiation; polar vortex; 1610 Global Change: Atmosphere; 0341 Atmospheric Composition and Structure: Middle atmosphere: constituent transport and chemistry; 0340 Atmospheric Composition and Structure: Middle atmosphere: composition and chemistry
Programme: 209
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Alexander, B.; Park, R.J.; Jacob, D.J.; Li, Q.B.; Yantosca, R.M.; Savarino, J.; Lee, C.C.W.; Thiemens, M.H. (2005). Sulfate formation in sea-salt aerosols: Constraints from oxygen isotopes. J. Geophys. Res., 110.
Abstract: We use observations of the mass-independent oxygen isotopic composition (?17O) of sulfate in the marine boundary layer (MBL) to quantify the sulfate source from aqueous SO2 (S(IV)) oxidation by O3 in alkaline sea-salt aerosols. Oxidation by O3 imparts a large ?17O signature to the resulting sulfate (8.8‰) relative to oxidation by H2O2 (0.9‰) or by OH or O2 (0‰). Ship data from two Indian Ocean Experiment (INDOEX) cruises in the Indian Ocean indicate ?17O values usually <1‰ in the submicron sulfate aerosol but considerable variability in the supermicron sulfate with frequent occurrences above 1‰ and up to 6.7‰. The large ?17O values are associated with high concentrations of sea-salt aerosols, providing evidence for the S(IV) + O3 pathway. We use a global chemical transport model (GEOS-CHEM) to interpret quantitatively the INDOEX observations and to assess the global importance of sulfate production in sea-salt aerosols. The model accounts for titration of sea-salt alkalinity in the MBL by uptake of acid gases (SO2, H2SO4, and HNO3), shutting down the S(IV) + O3 pathway. We find that this titration occurs rapidly over much of the oceans except at high latitudes (strong sea-salt emission) and is due to both the S(IV) + O3 reaction and HNO3 (g) condensation; that is, sulfate formation in sea-salt aerosols is limited by the alkalinity flux from the ocean and by competition for this alkalinity supply from HNO3 (g). The model is consistent with the ?17O magnitudes and patterns in the INDOEX data. Titration of alkalinity is critical for the success of the model simulation. Regeneration of sea-salt aerosol alkalinity by OH uptake is inconsistent with the ?17O observations in INDOEX. Model results indicate that sulfate production in sea-salt aerosols decreases MBL SO2 concentrations and gas phase H2SO4 production rates by typically 10–30% (up to >70%) and increases MBL sulfate concentrations by typically >10% (up to 30%). Globally, this mechanism contributes 9% of atmospheric sulfate production and 1% of the sulfate burden. The impact on H2SO4 (g) formation and implications for the potential formation of new particles in the MBL warrants inclusion in models examining the radiative effects of sulfate aerosols.
Keywords: atmospheric chemistry; aerosol formation; isotopes; 0305 Atmospheric Composition and Structure: Aerosols and particles; 0312 Atmospheric Composition and Structure: Air/sea constituent fluxes; 0365 Atmospheric Composition and Structure: Troposphere: composition and chemistry; 0490 Biogeosciences: Trace gases; 1041 Geochemistry: Stable isotope geochemistry
Programme: 399
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Robisson P. (1992). Vocalizations in Aptenodytes penguins: application of the two-voice theory. Auk, 109(3), 654–658.
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Landais, A.; Steffensen, J.P.; Caillon, N.; Jouzel, J.; Masson-Delmotte, V.; Schwander, J. (2004). Evidence for stratigraphic distortion in the Greenland Ice Core Project (GRIP) ice core during Event 5e1 (120 kyr BP) from gas isotopes. J. Geophys. Res., 109.
Abstract: The disturbed stratigraphy of the ice in the lowest 10% of the Greenland GRIP ice core has been previously demonstrated using gas measurements (?18O of O2 and CH4) on a few meters depth scale. However, rapid ice isotopic variations (on the scale of 20 cm) are experienced in the bottom of the GRIP ice core with complex chemical signatures that make them difficult to reconcile with a disturbed stratigraphy of the ice. This is the case for event 5e1, first described as a dramatic cooling 120 kyr BP. We analyzed at a 5 cm resolution the isotopic composition of the air from 2 m of the GRIP bottom ice core covering event 5e1. The ?15N measurements, combined with a basic firn modeling, lead to the solid conclusion that the rapid event 5e1 is not a climatic event. Rapid variations of ?18O of O2 (?18Oatm) are in agreement with a disturbed ice stratigraphy. However, the double peak shape of the ?18Oatm, recalling chemical data at the same depth, requires processes of diffusion after the mixing or even postcoring, placing limits to the interpretation of some classical paleoclimatic proxies in small scale mixed ice (<1 m).
Keywords: 1827 Hydrology: Glaciology; 3344 Meteorology and Atmospheric Dynamics: Paleoclimatology; 3349 Meteorology and Atmospheric Dynamics: Polar meteorology
Programme: 458
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Park, Y.-H. (2004). Determination of the surface geostrophic velocity field from satellite altimetry. J. Geophys. Res., 109.
Abstract: Presently available marine geoid models are not accurate enough to extract the mean surface circulation directly from satellite altimetry. A novel method for estimating the mean velocity field of major ocean current systems is derived from the free surface boundary condition. With a given quasi-geostrophic balance for the horizontal surface flow, a scaling analysis of this boundary condition indicates that although the vertical velocity w is mostly balanced by the local change of the free surface, ???/?t, useful information on the mean current ($\overline{u}$, $\overline{v}$) is contained in a small ageostrophic departure (???/?t ? w). Our method consists in the development of a simple algebraic equation with two unknowns ($\overline{u}$, $\overline{v}$) and an adjustable parameter $\widetilde{\alpha}$ associated with ???/?t, assuming that the latter is proportional to (???/?t ? w). Most interestingly, ???/?t and all other coefficients of the equation can be determined from altimetry. The altimeter data used is combined TOPEX/Poseidon-ERS gridded data, and the solution is obtained by least squares, minimizing the contribution from the time-variable part of the parameter $\widetilde{\alpha}$ and prescribing the zonal direction of the mean current. The method, which is found to be particularly useful for quasi-zonal high-energy current systems, has been validated against direct observations in the Gulf Stream and Southern Ocean. Comparisons with direct observations and Monte Carlo experiments suggest an overall solution error of about 10 cm s?1. Once calibrated against regional velocity statistics, this method will be able to determine from altimetry the mean or instantaneous surface velocity field down to the frontal scale, with a realism that has been inaccessible because of the geoid constraint.
Keywords: 4512 Oceanography: Physical: Currents; 4528 Oceanography: Physical: Fronts and jets; 4556 Oceanography: Physical: Sea level variations
Programme: 335
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Debayle, E.; Sambridge, M. (2004). Inversion of massive surface wave data sets: Model construction and resolution assessment. J. Geophys. Res., 109, B02316.
Abstract: A new scheme is proposed for the inversion of surface waves using a continuous formulation of the inverse problem and the least squares criterion. Like some earlier schemes a Gaussian a priori covariance function controls the horizontal degree of smoothing in the inverted model, which minimizes some artifacts observed with spherical harmonic parameterizations. Unlike earlier schemes the new approach incorporates some sophisticated geometrical algorithms which dramatically increase computational efficiency and render possible the inversion of several tens of thousands of seismograms in few hours on a typical workstation. The new algorithm is also highly suited to parallelization which makes practical the inversion of data sets with more than 50,000 ray paths. The constraint on structural and anisotropic parameters is assessed using a new geometric approach based on Voronoi diagrams, polygonal cells covering the Earth's surface. The size of the Voronoi cells is used to give an indication of the length scale of the structures that can be resolved, while their shape provides information on the variation of azimuthal resolution. The efficiency of the scheme is illustrated with realistic uneven ray path configurations. A preliminary global tomographic model has been built for SV wave heterogeneities and azimuthal variations through the inversion of 24,124 fundamental and higher-mode Rayleigh waveforms. Our results suggest that the use of relatively short paths (<10,000 km) in a global inversion should minimize multipathing, or focusing/defocusing effects and provide lateral resolution of a few hundred kilometers across the globe.
Keywords: 7218 Seismology: Lithosphere and upper mantle; 7255 Seismology: Surface waves and free oscillations; 7260 Seismology: Theory and modeling; 8180 Tectonophysics: Tomography
Programme: 133;906
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Rousseau, D.-D.; Duzer, D.; Etienne, J.-L.; Cambon, G.; Jolly, D.; Ferrier, J.; Schevin, P. (2004). Pollen record of rapidly changing air trajectories to the North Pole. J. Geophys. Res., 109.
Abstract: Tracing modern atmospheric dynamics is important for constraining models used in past climate reconstruction. However, these models must be verified by modern observations. We present the rapid changeover of two different air trajectories to the North Pole determined by studying the long distance transport of pollen. Samples were collected on a manned floating capsule drifting southward on the sea ice from the North Pole in 2002. It was observed that an air mass at 3000 m altitude transported birch and pine pollen released in Western Europe during week 22 (May 27). Two weeks later, during week 24 (June 10), alder, birch and willow pollen from eastern Siberia reached the drifting station with an air mass at 1000 m altitude. These particular patterns support independent investigations of air trajectories in the Arctic, especially the transport of anthropogenic pollutants such as sulfate and nitrate.
Keywords: 0305 Atmospheric Composition and Structure: Aerosols and particles; 0315 Atmospheric Composition and Structure: Biosphere/atmosphere interactions; 1620 Global Change: Climate dynamics; 3322 Meteorology and Atmospheric Dynamics: Land/atmosphere interactions
Programme: 349
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Meijer, Y.J.; Swart, D.P.J.; Allaart, M.; Andersen, S.B.; Bodeker, G.; Boyd, I.; Braathen, G.; Calisesi, Y.; Claude, H.; Dorokhov, V.; von der Gathen, P.; Gil, M.; Godin-Beekmann, S.; Goutail, F.; Hansen, G.; Karpetchko, A.; Keckhut, P.; Kelder, H.M.; Koelemeijer, R.; Kois, B.; Koopman, R.M.; Kopp, G.; Lambert, J.-C.; Leblanc, T.; McDermid, I.S.; Pal, S.; Schets, H.; Stubi, R.; Suortti, T.; Visconti, G.; Yela, M. (2004). Pole-to-pole validation of Envisat GOMOS ozone profiles using data from ground-based and balloon sonde measurements. J. Geophys. Res., 109.
Abstract: In March 2002 the European Space Agency (ESA) launched the polar-orbiting environmental satellite Envisat. One of its nine instruments is the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument, which is a medium-resolution stellar occultation spectrometer measuring vertical profiles of ozone. In the first year after launch a large group of scientists performed additional measurements and validation activities to assess the quality of Envisat observations. In this paper, we present validation results of GOMOS ozone profiles from comparisons to microwave radiometer, balloon ozonesonde, and lidar measurements worldwide. Thirty-one instruments/launch sites at twenty-five stations ranging from the Arctic to the Antarctic joined in this activity. We identified 6747 collocated observations that were performed within an 800-km radius and a maximum 20-hour time difference of a satellite observation, for the period between 1 July 2002 and 1 April 2003. The GOMOS data analyzed here have been generated with a prototype processor that corresponds to version 4.02 of the operational GOMOS processor. The GOMOS data initially contained many obviously unrealistic values, most of which were successfully removed by imposing data quality criteria. Analyzing the effect of these criteria indicated, among other things, that for some specific stars, only less than 10% of their occultations yield an acceptable profile. The total number of useful collocated observations was reduced to 2502 because of GOMOS data unavailability, the imposed data quality criteria, and lack of altitude overlap. These collocated profiles were compared, and the results were analyzed for possible dependencies on several geophysical (e.g., latitude) and GOMOS observational (e.g., star characteristics) parameters. We find that GOMOS data quality is strongly dependent on the illumination of the limb through which the star is observed. Data measured under bright limb conditions, and to a certain extent also in twilight limb, should be used with caution, as their usability is doubtful. In dark limb the GOMOS data agree very well with the correlative data, and between 14- and 64-km altitude their differences only show a small (2.5–7.5%) insignificant negative bias with a standard deviation of 11–16% (19–63 km). This conclusion was demonstrated to be independent of the star temperature and magnitude and the latitudinal region of the GOMOS observation, with the exception of a slightly larger bias in the polar regions at altitudes between 35 and 45 km.
Keywords: GOMOS; Envisat; ozone profile; validation; stratosphere; remote sensing; 0365 Atmospheric Composition and Structure: Troposphere—composition and chemistry; 0394 Atmospheric Composition and Structure: Instruments and techniques; 3360 Meteorology and Atmospheric Dynamics: Remote sensing; 3394 Meteorology and Atmospheric Dynamics: Instruments and techniques
Programme: 209
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Udisti, R.; Becagli, S.; Castellano, E.; Delmonte, B.; Jouzel, J.; Petit, J.R.; Schwander, J.; Stenni, B.; Wolff, E.W. (2004). Stratigraphic correlations between the European Project for Ice Coring in Antarctica (EPICA) Dome C and Vostok ice cores showing the relative variations of snow accumulation over the past 45 kyr. J. Geophys. Res., 109.
Abstract: High-resolution chemistry analysis and electrical measurements performed on two ice core records (European Project for Ice Coring in Antarctica (EPICA) Dome C and Vostok) spanning the last 45 kyr allow stratigraphic correlations by matching volcanic events. Several common events were identified along the two ice cores on the basis of acidity and sulphate spikes in snow layers. Timescales were matched through comparison with isotope (?D) profiles and using the Antarctic cold reversal (ACR) minimum, a 10Be peak, and a dust spike as temporal checkpoints. Ratios of relative snow accumulation at the two sites during the Holocene, in the glacial-interglacial transition and in the last part of the glacial period, were reconstructed by finding the best fit between Dome C and Vostok depths recording the same events. After accounting for thinning of the layers as they are buried within the glacier, the Dome C-Vostok accumulation ratio, expected to be roughly constant from the conventional accumulation-temperature-isotope approach, is 1.12 for the glacial period but increases to as much as 1.44 for a large part of the Holocene. Glaciological effects, mainly related to the geographic origin of the Vostok ice along the Ridge B-Vostok axis, can account for only a minor fraction of this change. Instead, we argue that accumulation variability between the cores stems from differential changes in atmospheric circulation during these respective climatic periods at the two sites. Regional changes in atmospheric circulation are proposed with a negative anomaly in Dome C, a positive accumulation anomaly in Vostok, or a combination of both during glacial climate. Our approach may help to improve ice core dating by: (1) revealing anomalies in accumulation-rate estimation based on the classical thermodynamic method and (2) supporting the necessity to take into account contributions due to changes in atmospheric circulation processes.
Keywords: 0325 Atmospheric Composition and Structure: Evolution of the atmosphere; 1620 Global Change: Climate dynamics; 1863 Hydrology: Snow and ice; 3344 Meteorology and Atmospheric Dynamics: Paleoclimatology; 9310 Information Related to Geographic Region: Antarctica
Programme: 960
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