Abstract. Clouds affect the Earth climate with an impact that depends on the cloud nature (solid/ liquid water). Although the Antarctic climate is changing rapidly, cloud observations are sparse over Antarctica due to few ground stations and satellite observations. The Concordia station is located on the East Antarctic Plateau (75° S, 123° E, 3233 m above mean sea level), one of the driest and coldest places on Earth. We used observations of clouds, temperature, liquid water and surface radiation performed at Concordia during 4 austral summers (December 2018–2021) to analyze the link between liquid water and temperature and its impact on surface radiation in the presence of supercooled liquid water (liquid water for temperature less than 0 °C) clouds (SLWCs). Our analysis shows that, within SLWCs, temperature logarithmically increases from -36.0 °C to -16.0 °C when liquid water path increases from 1.0 to 14.0 g m^-2, and SLWCs positively impact the net surface radiation, which logarithmically increases by 0.0 to 50.0 W m^-2 when liquid water path increases from 1.7 to 3.0 g m^-2. We finally estimate that SLWCs have a great potential radiative impact over Antarctica whatever the season considered, up to 5.0 W m^-2 over the Eastern Antarctic Plateau and up to 30 W m^-2 over the Antarctic Peninsula in summer.