Abstract: We investigate atmospheric properties of 35 stable RRab stars that possess the full ranges of period, light amplitude, and metal abundance found in Galactic RR Lyrae stars. Our results are derived from several thousand echelle spectra obtained over several years with the du Pont telescope of Las Campanas Observatory. Radial velocities of metal lines and the Hα line were used to construct curves of radial velocity versus pulsation phase. From these we estimated radial velocity amplitudes for metal lines (formed near the photosphere) and Hα Doppler cores (formed at small optical depths). We also measured Hα emission fluxes when they appear during primary light rises. Spectra shifted to rest wavelengths, binned into small phase intervals, and co-added were used to perform model atmospheric and abundance analyses. The derived metallicities and those of some previous spectroscopic surveys were combined to produce a new calibration of the Layden abundance scale. We then divided our RRab sample into metal-rich (disk) and metal-poor (halo) groups at [Fe/H] = −1.0; the atmospheres of RRab families, so defined, differ with respect to (a) peak strength of Hα emission flux, (b) Hα radial velocity amplitude, (c) dynamical gravity, (d) stellar radius variation, (e) secondary acceleration during the photometric bump that precedes minimum light, and (f) duration of Hα line-doubling. We also detected Hα line-doubling during the