Abstract: A record of atmospheric carbon dioxide (CO2) concentration during the transition from the Last Glacial Maximum to the Holocene, obtained from the Dome Concordia, Antarctica, ice core, reveals that an increase of 76 parts per million by volume occurred over a period of 6000 years in four clearly distinguishable intervals. The close correlation between CO2 concentration and Antarctic temperature indicates that the Southern Ocean played an important role in causing the CO2 increase. However, the similarity of changes in CO2 concentration and variations of atmospheric methane concentration suggests that processes in the tropics and in the Northern Hemisphere, where the main sources for methane are located, also had substantial effects on atmospheric CO2 concentrations

Abstract: Atmospheric nitrogen oxides (NOx =NO+ NO2) play a pivotal role in the cycling of reactive nitrogen (ultimately deposited as nitrate) and the oxidative capacity of the atmosphere. Combined measurements of nitrogen and oxygen stable isotope ratios of nitrate collected in the Arctic atmosphere were used to infer the origin and fate of NOx and nitrate on a seasonal basis. In spring, photochemically driven emissions of reactive nitrogen from the snowpack into the atmosphere make local oxidation of NOx by bromine oxide the major contributor to the nitrate budget. The comprehensive isotopic composition of nitrate provides strong constraints on the relative importance of the key atmospheric oxidants in the present atmosphere, with the potential for extension into the past using ice cores.

Abstract: Measurements of midday vertical atmospheric CO2 distributions reveal annual-mean vertical CO2 gradients that are inconsistent with atmospheric models that estimate a large transfer of terrestrial carbon from tropical to northern latitudes. The three models that most closely reproduce the observed annual-mean vertical CO2 gradients estimate weaker northern uptake of -1.5 petagrams of carbon per year (Pg C year-1) and weaker tropical emission of +0.1 Pg C year-1 compared with previous consensus estimates of -2.4 and +1.8 Pg C year-1, respectively. This suggests that northern terrestrial uptake of industrial CO2 emissions plays a smaller role than previously thought and that, after subtracting land-use emissions, tropical ecosystems may currently be strong sinks for CO2.

Abstract: The Northern Hemisphere hydrological cycle is a key factor coupling ice sheets, ocean circulation, and polar amplification of climate change. Here we present a Northern Hemisphere deuterium excess profile covering one climatic cycle, constructed with the use of {delta}18O and {delta}D Greenland Ice Core Project (GRIP) records. Past changes in Greenland source and site temperatures are quantified with precipitation seasonality taken into account. The imprint of obliquity is evidenced in the site-to-source temperature gradient at orbital scale. At the millennial time scale, GRIP source temperature changes reflect southward shifts of the geographical locations of moisture sources during cold events, and these rapid shifts are associated with large-scale changes in atmospheric circulation.

Abstract: Many peridotite xenoliths sampled at ocean islands appear to have strongly refractory major element and modal compositions. To better constrain the chemistry, abundance and origin of these ultra-refractory rocks we compiled a large number of data for xenoliths from nine groups of ocean islands. The xenoliths were filtered petrographically for signs of melt infiltration and modal metasomatism, and the samples affected by these processes were excluded. The xenolith suites from most ocean islands are dominated by ultra-refractory harzburgites. Exceptions are the Hawaii and Tahiti peridotites, which are more fertile and contain primary clinopyroxene, and the Cape Verde suite, which contains both ultra-refractory and more fertile xenoliths. Ultra-refractory harzburgites are characterized by the absence of primary clinopyroxene, low whole-rock Al2O3, CaO, FeO/MgO and heavy rare earth element (HREE) concentrations, low Al2O3 in orthopyroxene (generally < 3 wt %), high Cr-number in spinel (0{middle dot}3-0{middle dot}8) and high forsterite contents in olivine (averages > 91{middle dot}5). They are therefore on average significantly more refractory than peridotites dredged and drilled from mid-ocean ridges and fracture zones. Moreover, their compositions resemble those of oceanic forearc peridotites. The formation of ultra-refractory ocean island harzburgites requires potential temperatures above those normally observed at modern mid-ocean ridges, and/or fluid fluxed conditions. Some ultra-refractory ocean island harzburgites give high Os model ages (up to 3300 Ma), showing that their formation significantly pre-dates the oceanic crust in the area. A genetic relationship with the host plume is considered unlikely based on textural observations, equilibration temperatures and pressures, inferred physical properties, and the long-term depleted Os and Sr isotope compositions of some of the harzburgites. Although we do not exclude the possibility that some ultra-refractory ocean island harzburgites have formed at mid-ocean ridges, we favor a model in which they formed in a process spatially and temporally unrelated to the formation of the oceanic plate and the host plume. As a result of their whole-rock compositions, ultra-refractory harzburgites have a very high solidus temperature at a given pressure, low densities and very high viscosities, and will tend to accumulate at the top of the convecting mantle. They may be preserved as fragments in the convecting mantle over long periods of time and be preferentially incorporated into newly formed lithosphere.