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Author |
Genthon C. & Armengaud A. |
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Title |
Radon 222 as a comparative tracer of transport and mixing in two general circulation models of the atmosphere. |
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Journal Article |
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Year |
1995 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
100 |
Issue |
d2 |
Pages |
2849-2866 |
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146 |
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0148-0227 |
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yes |
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1255 |
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Author |
Etheridge D.M., Steele L.P., Langenfelds R.L., Francey R.J., Barnoal J.M. & Morgan V.I. |
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Title |
Natural and anthropogenic changes in atmospheric CO2 over the last 1000 years from air in Antarctic ice and firn. |
Type |
Journal Article |
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Year |
1996 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
101 |
Issue |
d2 |
Pages |
4115-4128 |
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159 |
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0148-0227 |
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yes |
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1778 |
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Sturges W.T., Mcintre H.P., Penkett S.A., Chappellaz J., Barnola J.M., Mulvaney R., Atlas E. & Stroud V. |
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Title |
Methyl bromide, other brominated methanes, and methyl iodide in polar firn air. |
Type |
Journal Article |
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Year |
2001 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
106 |
Issue |
d2 |
Pages |
1595-1606 |
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902 |
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0148-0227 |
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yes |
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2275 |
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Author |
Krinner G., Raynaud D., Outriaux C. & Dang H. |
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Title |
Simulations of the Last Glacial Maximum ice sheet surface climate : Implications for the interpretation of ice core air content. |
Type |
Journal Article |
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Year |
2000 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
105 |
Issue |
d2 |
Pages |
2059-2070 |
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902 |
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0148-0227 |
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yes |
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2279 |
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Author |
Schmidt, M., R. Graul, et al. |
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Title |
The Schauinsland CO2 record: 30 years of continental observations and their implications for the variability of the European CO2 budget. |
Type |
Journal Article |
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Year |
2003 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
108 |
Issue |
d19 |
Pages |
4619 |
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439 |
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0148-0227 |
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yes |
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4168 |
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Author |
Genthon C. & Krinner G. |
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Title |
Antarctic surface mass balance and systematic biases in GCMs. |
Type |
Journal Article |
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Year |
2001 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
106 |
Issue |
d18 |
Pages |
20653-20664 |
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Abstract |
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Programme |
902 |
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0148-0227 |
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yes |
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Serial |
2270 |
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Author |
Braünlich M., Abbalin O., Marik T., Jöckel P., M Brenninkmeijer C.A., Chappellaz J., Barnola J.M., Mulvaney R. & Sturges W.T. |
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Title |
Changes in the global atmospheric methane budget over the last decades inferred from 13C and D isotopic analysis of Antarctic firn air. |
Type |
Journal Article |
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Year |
2001 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
106 |
Issue |
d17 |
Pages |
20465-20481 |
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902 |
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ISSN |
0148-0227 |
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Approved |
yes |
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Call Number |
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Serial |
2268 |
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Author |
Leroux C., Deuze J.L., Goloub P., Sergent C. & Fily M. |
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Title |
Ground measurements of the polarized bidirectional reflectance of snow in the middle infrared spectral domain: Comparisons with model results. |
Type |
Journal Article |
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Year |
1998 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
103 |
Issue |
d16 |
Pages |
19721-11973 |
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Abstract |
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Programme |
961 |
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ISSN |
0148-0227 |
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yes |
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Call Number |
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Serial |
2314 |
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Author |
Rinaldi Matteo, Decesari Stefano, Carbone Claudio, Finessi Emanuela, Fuzzi Sandro, Ceburnis Darius, O'Dowd Colin D, Sciare Jean, Burrows John P, Vrekoussis Mihalis, Ervens Barbara, Tsigaridis Kostas, Facchini Maria Cristina, |
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Title |
Evidence of a natural marine source of oxalic acid and a possible link to glyoxal
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Type |
Journal Article |
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Year |
2011 |
Publication |
J. Geophys. Res. |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
116 |
Issue |
D16 |
Pages |
D16204- |
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Keywords |
SOA, cloud processes, glyoxal, marine aerosol, oxalic acid, 0305 Atmospheric Composition and Structure: Aerosols and particles (0345, 4801, 4906), 0320 Atmospheric Composition and Structure: Cloud physics and chemistry, 0322 Atmospheric Composition and Structure: Constituent sources and sinks, 3311 Atmospheric Processes: Clouds and aerosols, |
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Abstract |
This paper presents results supporting the existence of a natural source of oxalic acid over the oceans. Oxalate was detected in “clean-sector” marine aerosol samples at Mace Head (Ireland) (5320′N, 954′W) during 2006, and at Amsterdam Island (3748′S, 7734′E) from 2003 to 2007, in concentrations ranging from 2.7 to 39 ng m-3 and from 0.31 to 17 ng m-3, respectively. The oxalate concentration showed a clear seasonal trend at both sites, with maxima in spring-summer and minima in fall-winter, being consistent with other marine biogenic aerosol components (e.g., methanesulfonic acid, non-sea-salt sulfate, and aliphatic amines). The observed oxalate was distributed along the whole aerosol size spectrum, with both a submicrometer and a supermicrometer mode, unlike the dominant submicrometer mode encountered in many polluted environments. Given its mass size distribution, the results suggest that over remote oceanic regions oxalate is produced through a combination of different formation processes. It is proposed that the cloud-mediated oxidation of gaseous glyoxal, recently detected over remote oceanic regions, may be an important source of submicrometer oxalate in the marine boundary layer. Supporting this hypothesis, satellite-retrieved glyoxal column concentrations over the two sampling sites exhibited the same seasonal concentration trend of oxalate. Furthermore, chemical box model simulations showed that the observed submicrometer oxalate concentrations were consistent with the in-cloud oxidation of typical marine air glyoxal mixing ratios, as retrieved by satellite measurements, at both sites.
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415 |
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AGU |
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0148-0227 |
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yes |
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3251 |
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Author |
Petersen A.C., Spee E.J., Van Dop H. & Hundsdorfer W. |
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Title |
An evaluation and intercomparison of four new advection schemes for use in global chemistry models. |
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Journal Article |
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Year |
1998 |
Publication |
Journal of geophysical research-atmospheres |
Abbreviated Journal |
J. Geophys. Res. |
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Volume |
103 |
Issue |
d15 |
Pages |
19253-19269 |
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344 |
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0148-0227 |
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yes |
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781 |
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