Abstract: A primary goal of developing the CO2 atmospheric measurement network is to better characterize the sources and sinks of atmospheric CO2. Atmospheric transport models can be used to interpret atmospheric measurements in terms of surface fluxes using inverse methodology. In this paper we present a three-dimensional (3-D) inversion of CO2 measurements in order to infer annual sources and sinks of CO2 at a continental scale (continents and ocean basins) for a climatological year representing the 1985–1995 period. Solving this inverse problem requires (1) a data space representing monthly CO2 measurements, here at 77 sites (surface, ships, planes), (2) a flux space describing a priori fluxes between carbon reservoirs, and (3) a 3-D transport model linking the flux space to the data space. Knowledge of these three elements, together with their associated errors, allows one to reduce the uncertainties of the CO2 sources and sinks. In the 1985–1995 period, for our control inversion, the global continental sink is found to be 2.7±1.5 Gt C yr1 for an optimized deforestation source of 1.4±0.6 Gt C yr1, yielding a net land uptake of 1.3±1.6 Gt C yr1 (fossil fuel removed). The continental partition of this budget is (in units of Gt C yr1): Arctic +0.2±0.3, North America ?0.5±0.6, Europe ?0.3±0.8, north Asia ?1.5±0.7, tropics (except Asia) +0.3±0.9, tropical Asia +0.8±0.4, and Southern Hemisphere ?0.1±0.3. The inferred partition for the controversial Northern Hemisphere CO2 sink reveals that a major sink is located over the north Asia continent. For oceans we find a net global sink of 1.5±0.5 Gt C yr1 with the following partition (in units of Gt C yr1): North Pacific ?0.3±0.2, North Atlantic ?0.8±0.3, equator +0.6±0.2, 20°S–50°S oceans ?0.9±0.3, and austral ocean ?0.1±0.1.

Abstract: Temperature profiles measurements are performed daily (00:00 UT) in Dumont d'Urville (66°40' S, 140°01' E) by Météo-France, using standard radiosondes, since the International Geophysical Year in 1957. Yet, due to a 16 years data gap between 1963 and 1978, the entire dataset is only used for a qualitative overview. Only the most recent series, between 1979 and 2008, is used to investigate the inter-annual stratospheric temperatures variability. Over Dumont d'Urville, at the edge of the vortex, the annual mean temperature cooling of about 1 K/decade at 20 km is the result of the cooling trends between 0.5 and 1.4 K/decade, in summer and autumn and a warming of about 1.1 K/decade in spring. These values are consistent with values obtained using data from inner vortex stations, but with smaller amplitude. No statistically significant trend is detected in winter. We propose here the first attempt to link stratospheric temperature trends to Polar Stratospheric Cloud (PSC) trends in Antarctica based on the only continuous 20 years database of PSC lidar detection. Despite the absence of mean temperature trend during winter, the occurrence of temperatures below the NAT threshold between 1989 and 2008 reveals a significant trend of about +6%/decade. The PSCs occurrences frequency exhibits a concomitant trend of about +3%/decade, although not statistically significant. Yet, this is consistent with results obtained in the Northern Hemisphere. Such a possible positive trend in PSC occurrence has to be further explored to be confirmed or invalidated. If confirmed, this PSC trend is likely to have strong impacts, both on ozone recovery and climate evolution in Antarctica. The study also reveals the importance of trends on extreme temperatures, and not only on mean temperatures.

Abstract: This modeling study was motivated by the recent publication of year-round records of dimethylsulfide (DMS) and dimethylsulfoxide (DMSO) in Antarctica, completing the available series of sulfate and methanesulfonic acid (MSA). Sulfur chemistry has been incorporated in the Laboratoire de Météorologie Dynamique-Zoom Tracers (LMD-ZT) Atmospheric General Circulation Model (AGCM), with high-resolution and improved physics at high-southern latitudes. The model predicts the concentration of six major sulfur species through emissions, transport, wet and dry deposition, and chemistry in both gas and aqueous phases. Model results are broadly realistic when compared with measurements in air and snow or ice, as well as to results of other modeling studies, at high- and middle-southern latitudes. Atmospheric MSA concentrations are underestimated and DMSO concentrations are overestimated in summer, reflecting the lack of a DMSO heterogeneous sink leading to MSA. Experiments with various recently published estimates of the rate of this sink are reported. Although not corrected in this work, other defects are identified and discussed: DMS concentrations are underestimated in winter, MSA and non-sea-salt (nss) sulfate concentrations may be underestimated at the South Pole, the deposition scheme used in the model may not be adapted to polar regions, and the model does not adequately reproduces interannual variability. Oceanic DMS sources have a major contribution to the variability of sulfur in these regions. The model results suggest that in a large part of central Antarctica ground-level atmospheric DMS concentrations are larger in winter than in summer. At high-southern latitudes, high loads of DMS and DMSO are found and the main chemical sink of sulfur dioxide (SO2) is aqueous oxidation by ozone (O3), whereas oxidation by hydrogen peroxide (H2O2) dominates at the global scale. A comprehensive modeled sulfur budget of Antarctica is provided.

Abstract: Simulations of ozone loss rates using a three-dimensional chemical transport model and a box model during recent Antarctic and Arctic winters are compared with experimental loss rates. The study focused on the Antarctic winter 2003, during which the first Antarctic Match campaign was organized, and on Arctic winters 1999/2000, 2002/2003. The maximum ozone loss rates retrieved by the Match technique for the winters and levels studied reached 6 ppbv/sunlit hour and both types of simulations could generally reproduce the observations at 2-sigma error bar level. In some cases, for example, for the Arctic winter 2002/2003 at 475 K level, an excellent agreement within 1-sigma standard deviation level was obtained. An overestimation was also found with the box model simulation at some isentropic levels for the Antarctic winter and the Arctic winter 1999/2000, indicating an overestimation of chlorine activation in the model. Loss rates in the Antarctic show signs of saturation in September, which have to be considered in the comparison. Sensitivity tests were performed with the box model in order to assess the impact of kinetic parameters of the ClO-Cl2O2 catalytic cycle and total bromine content on the ozone loss rate. These tests resulted in a maximum change in ozone loss rates of 1.2 ppbv/sunlit hour, generally in high solar zenith angle conditions. In some cases, a better agreement was achieved with fastest photolysis of Cl2O2 and additional source of total inorganic bromine but at the expense of overestimation of smaller ozone loss rates derived later in the winter.

Abstract: A tentative age scale (EDC1) for the last 45 kyr is established for the new 788-m EPICA Dome C ice core using a simple ice flow model. The age of volcanic eruptions, the end of the Younger Dryas event, and the estimated depth and age of elevated 10Be, about 41 kyr ago were used to calibrate the model parameters. The uncertainty of EDC1 is estimated to ± 10 yr for 0 to 700 yr BP, up to ± 200 yr back to 10 kyr BP, and up to ± 2 kyr back to 41 kyr BP. The age of the air in the bubbles is calculated with a firn densification model. In the Holocene the air is about 2000 yr younger than the ice and about 5500 yr during the last glacial maximum.