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Author (up) Tackett, P.J.; Cavender, A.E.; Keil, A.D.; Shepson, P.B.; Bottenheim, J.W.; Morin, S.; Deary, J.; Steffen, A.; Doerge, C.
Title A study of the vertical scale of halogen chemistry in the Arctic troposphere during Polar Sunrise at Barrow, Alaska Type Journal Article
Year 2007 Publication Journal of geophysical research-atmospheres Abbreviated Journal J. Geophys. Res.
Volume 112 Issue Pages
Keywords Arctic; halogen chemistry; vertical profiles; 0365 Atmospheric Composition and Structure: Troposphere: composition and chemistry; 0736 Cryosphere: Snow; 0738 Cryosphere: Ice; 0312 Atmospheric Composition and Structure: Air/sea constituent fluxes; 0322 Atmospheric Composition and Structure: Constituent sources and sinks
Abstract The vertical extent and impact of halogen chemistry in the Arctic springtime was investigated through balloon-based measurement of several atmospheric chemical components. Various chemical species, including volatile organic compounds (VOCs), ozone, and elemental mercury, that are modified by halogen chemistry were measured from the surface to ?300 m during late March through mid-April 2005 in Barrow, Alaska. It is observed that the halogen chemistry appears to be most active in the lowest 100–200 m of the atmosphere. The Hg vertical concentration profiles are consistent with destruction by chemistry that evolves from a species emitted from the snowpack, most likely Br2 and BrCl, and the VOC profiles also demonstrate the limited vertical scale of halogen-initiated chemistry taking place above the Arctic snowpack.
Programme 457
Campaign
Address
Corporate Author Thesis
Publisher American Geophysical Union Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0148-0227 ISBN Medium
Area Expedition Conference
Notes Approved yes
Call Number IPEV @ Thierry.Lemaire @ Serial 5635
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